Publications

24.  Kumar, P.; SantaLucia, D.J.; Kaniewska-Laskowska, K.; Lindeman, S. V.; Ozarowski, A.; Krzystek, J.; Ozerov, M.; Telser, J.; Berry, J.F.;* Fiedler, A.T.*  “Probing the Magnetic Anisotropy of Co(II) Complexes Featuring Redox-​Active Ligands.” Inorganic Chemistry 2020, 59, 16178-16193.

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23. Fischer, A.A.; Miller, J.R.; Jodts, R.J.; Ekanayake, D.M.; Lindeman, S.V.; Brunold, T.C.;* Fiedler, A.T.* “Spectroscopic and Computational Comparisons of Thiolate-Ligated Ferric Nonheme Complexes to Cysteine Dioxygenase: Second-Sphere Effects On Substrate (Analogue) Positioning.” Inorganic Chemistry 2019, 58, 16487-16499. ic9b02432_0011


22. Kumar, P.; Lindeman, S.V.; Fiedler, A.T.* “Cobalt Superoxo and Alkylperoxo Complexes Derived from Reaction of Ring-Cleaving Dioxygenase Models with O2.” Journal of the American Chemical Society 2019, 141, 10984-10987. 

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21. Fischer, A.A.; Lindeman, S.V.; Fiedler, A.T.*  “A Synthetic Model of the Nonheme Iron–Superoxo Intermediate of Cysteine Dioxygenase.”  Chemical Communications 2018, 54, 11344-11347. 

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20. Wang, D.; Ekanayake, D.M; Lindeman, S.V.; Verani, C.N.;* Fiedler, A.T.*  “Multielectron Redox Chemistry of Transition Metal Complexes Supported by a Non-innocent N3P2 Ligand: Synthesis, Characterization, and Catalytic Properties.”  European Journal of Inorganic Chemistry 2018, 4133-4141.

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19.  Fischer, A.A.; Lindeman, S.V., Fiedler, A.T.* “Spectroscopic and Computational Studies of Reversible O2 Binding by a Cobalt Complex Relevant to Cysteine Dioxygenase.”  Dalton Transactions 2017, 46, 13229-13241.  (Invited contribution to “Frontiers in Spectroscopic Techniques in Inorganic Spectroscopy” themed issue). 

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18.  Kpogo, K.K.; Mazumder, S.; Wang, D.; Schlegel, H.B.;* Fiedler, A.T.;* Verani, C.N.* “Bimetallic Cooperativity in Proton Reduction with an Amido-Bridged Cobalt Catalysts.” Chemistry – A European Journal 2017, 23, 9272-9279. 

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17. Stein, N.; Gumataotao, N.; Hajnas, N.; Wu, R.; Lankathilaka, K.P.W.; Bornscheuer, U.T.; Liu, D.; Fiedler, A.T.*; Holz, R.C.*; Bennett, B.* “Multiple States of Nitrile Hydratase from Rhodococcus equi TG328-2: Structural and Mechanistic Insights from EPR and DFT Studies.”  Biochemistry 2017, 56, 3068-3077.  

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16. Fiedler, A. T.*; Fischer, A. A. “Oxygen Activation by Mononuclear Mn, Co, and Ni Centers in Biology and Synthetic Complexes” Journal of Biological Inorganic Chemistry 2017, 22, 407-425.  (Invited review article to the special issue: “60 Years of Oxygen Activation.”). 


15. Fischer, A. A.; Stracey, N.; Lindeman, S. V.; Brunold, T. C.; Fiedler, A.T.* “Synthesis, X-ray Structures, Electronic Properties, and O2/NO Reactivities of Thiol Dioxygenase Active-Site Models” Inorganic Chemistry 2016, 55, 11839-11853.

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14. Baum, A.E.; Lindeman, S.V.; Fiedler, A.T.* “Mononuclear Iron-(hydro/semi)quinonate Complexes Featuring Neutral and Charged Scorpionates: Synthetic Models of Intermediates in the Hydroquinone Dioxygenase Mechanism” European Journal of Inorganic Chemistry 2016, 2455-2464.

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13. Wang, D.; Lindeman, S.V.; Fiedler, A.T.* “Bimetallic Complexes Supported by a Redox-Active Ligand with Fused Pincer-Type Coordination Sites” Inorganic Chemistry 2015, 54, 8744-8754.
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12. Lane, A.C.; Barnes, C.L.; Antholine, W.E.*; Wang, D.; Fiedler, A.T.*; Walensky, J.R.* “Di- and Trinuclear Mixed-Valence Copper Amidinate Complexes from Reduction of Iodine” Inorganic Chemistry 2015, 54, 8509-8517.
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11. Baum, A.E.; Park, H. Lindeman, S.V.; Fiedler, A.T.* “Synthesis and Spectroscopic Characterization of High-Spin Mononuclear Fe(II) p-Semiquinonate Complexes” Inorganic Chemistry 2014, 53, 12240-12242.


10. Wang, D.; Lindeman, S.V.; Fiedler, A.T.* “Synthesis of homo- and heterobimetallic Ni(II)-M(II) (M = Fe, Co, Ni, Zn) complexes based on an unsymmetric ligand framework: Structures, spectroscopic features and redox properties” Inorganica Chimica Acta 2014, 421, 559-567.

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9. Bittner, M.M; Lindeman, S.V.; Popescu, C.V. Fiedler, A.T* “Dioxygen Reactivity of Biomimetic Fe(II) Complexes with Noninnocent Catecholate, o-Aminophenolate, and o-Phenylenediamine Ligands” Inorganic Chemistry 2014, 53, 4047-4061.2014 Inorg Chem TOC


8. Baum, A.E.; Lindeman, S.V.; Fiedler, A.T.* “Preparation of a Semiquinonate- Bridged Diiron(II) Complex and Elucidation of its Geometric and Electronic Structures.” Chemical Communications 2013, 49, 6531-6533.2013 ChemComm TOC


7.   Wang, D.; Lindeman, S.V., Fiedler, A.T.* “Intramolecular Hydrogen Bonding in Cu(II) Complexes with 2,6-Pyridinedicarboxamide Ligands:  Synthesis, Structural Characterization, and Physical Properties.”  European Journal of Inorganic Chemistry 2013, 4473-4484. 2013 EJIC TOC


6.   Bittner, M.M.; Kraus, D.; Lindeman, S.V.; Popescu, C.V.;* Fiedler, A.T. *“Synthetic, Spectroscopic and DFT Studies of Iron Complexes with Iminobenzo(semi)quinone Ligands:  Implications for o-Aminophenol Dioxygenases.”Chemistry – A European Journal 201319, 9686-9698.

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5.   Park, H.; Bittner, M.M.; Baus, J.S.; Lindeman, S.V.; Fiedler, A.T.* “Fe(II) Complexes That Mimic the Active Site Structure of Acetylacetone Dioxygenase: Oand NO Reactivity.”  Inorganic Chemistry 2012, 51, 10279-10289.

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4.   Baum, A.E.; Park, H.; Wang, D.; Lindeman, S.V.; Fiedler, A.T.* “Structural, Spectroscopic, and Electrochemical Properties of Nonheme Fe(II)-Hydroquinonate Complexes: Synthetic Models of Hydroquinone Dioxygenases.”  Dalton Transactions 201241, 12244-12253.2012 Dalton TOC


3.   Bittner, M.M.; Lindeman, S.V.; Fiedler, A.T.* “A Synthetic Model of the Putative Fe(II)-Iminobenzo-semiquinonate Intermediate in the Catalytic Cycle of o-Aminophenol Dioxygenases.”  Journal of the American Chemical Society 2012134, 5460-5463.  (This paper was selected for the “Models of Metalloenzymes” virtual issue). 2012 JACS TOC


2.   Bittner, M.M.; Baus, J.S.; Lindeman, S.V.; Fiedler, A.T.*  “Synthesis and Structural Characterization of Iron(II) Complexes with Tris(imidazolyl)phosphane Ligands:  A Platform for Modeling the 3-Histidine Facial Triad of Nonheme Fe Dioxygenases.” European Journal of Inorganic Chemistry 2012, 1848-1856.  2012 EJIC TOC


1.   Park, H.; Baus, J.S.; Lindeman, S.V.; Fiedler, A.T.* Synthesis and Characterization of Fe(II) b-Diketonate Complexes with Relevance to Acetylacetone Dioxygenase:  Insights into the Electronic Properties of the 3-His Facial Triad.” Inorganic Chemistry 2011, 50, 11978–11989. 2011 Inorg Chem TOC